can you please check the document you are trying to post G/L accounts ( Debit & credit) defined in classify G/L Accounts for document splitting, it should not be same.
Debit G/L account should be defined under one category and credit should be under another category.
Can I know did you enter any cost center while doing postings.
At the time of posting if you don't enter any profit center or cost center details the system will picks automatically the default profit center defined in FAGL3KEH,other wise it takes what you specified at transaction level.
If you mentioned cost center in transaction, however that cost center is created basing on profit center so it picks the profit center assigned to the cost center.
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