Hello Akhilesh,
I could see you have opened a case with support and the engineer's reply was the bellow. Therefore, I'm adding it as an answer in the Community so others can benefit from this information as well. 🙂
"Referred to your description, it seems to be the same behavior as explained in the note 79618 - Billing block in customer master and sales order, there are two different types of billing block:
1. The billing block in the customer master is intended to generally block a customer for the billing transaction.
2. On the other hand, the billing block in the sales order is used to block only the current document for billing.
They are two kinds of field even they all call "Billing block", so this field should not be copied from customer master data into the sales order. If you would need to fulfill that requirement but do not want to set it on document type level, you may consider to apply custom logic in userexit, such as "USEREXIT_MOVE_FIELD_TO_VBAK".
For further details, you should contact your local development team or local consultants."
Kind regards,
Vic
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